Conference Agenda

Session
MS-20: Dynamic frameworks
Time:
Monday, 16/Aug/2021:
10:20am - 12:45pm

Session Chair: Christopher SUMBY
Session Chair: Michael John Zaworotko
Location: Club C

50 1st floor

Invited: Hoi Ri Moon (Republic of Korea), Yao Chen (China)


Session Abstract

Dynamic behaviour and structural flexibility are important properties of extended frameworks, such as Metal-organic Frameworks (MOFs), and in porous solids composed of molecular materials, like Metal-organic Polyhedra (MOPs) and Porous Organic Cages (POCs).  In extended materials this can be realised as breathing or stimulus-response, providing access to unexpected porosity or sensing behaviour.  For molecular materials, which lack strong bonding between components, structural transformations in response to sorbents can be profound, leading to advantageous sorption and separation processes. This session will examine the dynamic behaviour and structural flexibility of both molecular and extended porous frameworks, with a focus on phase transitions, which can be monitored by X-ray crystallography.

For all abstracts of the session as prepared for Acta Crystallographica see PDF in Introduction, or individual abstracts below.


Introduction
Presentations
10:20am - 10:25am

Introduction to session

Christopher Sumby, Michael John Zaworotko



10:25am - 10:55am

Flexible Metal-Organic Frameworks for Hydrogen Isotope Separation

Hoi Ri Moon

Department of Chemistry, Ulsan National Institute of Science and Technology, Ulsan, Korea, Republic of (South Korea)



10:55am - 11:25am

Novel composite platform: Biomolecules-incorporation for biocatalysis, separation and biopharmaceutical formulations

Yao Chen

Nankai University, Tianjin, China, People's Republic of



11:25am - 11:45am

Dynamic frameworks: the role of non-covalent interactions

Susan Ann Bourne

University of Cape Town, Cape Town, South Africa



11:45am - 12:05pm

Synthesis and structural properties of isostructural Zn(II) M12L8 poly-[n]-catenane using the 2,4,6-tris(4-pyridyl)benzene (TPB) ligand

Javier Marti-Rujas, Stefano Torresi, Antonino Famulari

Politecnico di Milano, Milan, Italy



12:05pm - 12:25pm

Cocrystallization, high pressure/low temperature behaviour and vapochromism in a family of aurophilic copper-gold supramolecular networks.

Emanuele Priola1, Nadia Curetti2, Domenica Marabello1, Jacopo Andreo3, Alessia Giordana1, Lorenza Operti1, Piera Benna2, Eliano Diana1

1Department of Chemistry, Università di Torino, Via Pietro Giuria 7, 10125 Torino, Italy; 2Department of Earth sciences, University of Torino, Via Valperga Caluso 35, 10125, Turin, Italy; 33Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale G. P. Usberti 17A, 43100 Parma, Italy



12:25pm - 12:45pm

Structural modifications occurring during the water sorption processes on a potential material for autonomous indoor humidity control

Patrice Kenfack Tsobnang1, Thiery Yannick Sakam Nchedoung1, Dominik Fröhlich2, Emrah Hastürk3, Florence Porcher4, Christoph Janiak3

1University of Dschang, Department of Chemistry, PO Box 67, Dschang, Cameroon; 2Fraunhofer-Institut for Solar Energy Systems ISE, Division Thermal Systems and Buildings, Heidenhofstraße 2, 79110 Freiburg, Germany; 3Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany; 4Laboratoire Léon Brillouin (LLB), UMR 12 CEA/CNRS, Bât. 563 CEA Saclay, 91191 Gif-sur-Yvette cedex, France