Conference Agenda

Session
MS-76(59b): Crystal chemistry with emerging technology II
Time:
Friday, 20/Aug/2021:
10:20am - 12:45pm

Session Chair: Consiglia Tedesco
Session Chair: Toru Asahi
Location: Club C

50 1st floor

Session Abstract

Development and understanding of solid state chemistry is the key to promote the challenges of emerging and sustainable technologies. 

Functional materials and devices with targeted applications in several fields as catalysis, purification, separation, electronics, medicine, etc. will be the focus of the MS. Experimental, theoretical, and their merged studies are welcomed to the MS


Introduction
Presentations
10:20am - 10:25am
ID: 1807 / MS-76(59b): 1
Introduction
Oral/poster

Introduction to session

Consiglia Tedesco, Toru Asahi



10:25am - 10:55am
ID: 860 / MS-76(59b): 2
Chemical crystallography, crystal structures
Oral/poster
MS: Crystal chemistry with emerging technology, Polymorphism and structural transformation of organic crystals from synthesis to characterization
Keywords: in situ synthesis; crystallization; kinetic; X-ray diffraction

In situ study of chemical synthesis using high-energy X-ray diffraction on beamline I12 at Diamond Light Source

Oxana V. Magdysyuk, Thomas Connolley, Robert Atwood, Stefan Michalik

Diamond Light Source Ltd., Didcot, United Kingdom

The crystallisation of various materials from solution is an important area of study in the field of in situ X‑ray diffraction. Beamline I12 at Diamond synchrotron offers the improved experimental capabilities for in situ investigation of the large-scale synthesis process in unprecedented detail [1]. Time-resolved monochromatic high energy X-ray diffraction on the Beamline I12 is a fast and efficient method for investigation of crystallization allowing the detection of crystalline intermediates, formulating an idea about the crystallization mechanism, and the assessment of individual reaction parameters, i.e., reaction rate constants and activation energies. Thus, the optimization of the synthesis conditions of new compounds can be achieved. The high X-ray flux on the beamline I12 allows real-time monitoring the synthesis in the large containers, including standard laboratory metal autoclaves. Using monochromatic X-rays for the synchrotron experiments produces the high-quality diffraction data that permits the full structural refinements to be undertaken on metastable materials observed during the reaction.

The simplest experimental setup for low temperature in situ diffraction experiments is a metal heating block, which allows measurements during the synthesis from room temperature to approx. 90oC. It can be used with magnetic hotplate stirrer, allowing to mix substance during the measurements providing the homogeneous distribution of material in the reaction tube. For synthesis at temperatures close to the room temperature, the remotely controlled syringe pump can be used allowing simultaneous or sequential adding the reactants, thus permitting the investigation of the reaction in the controlled way from the very early stages [2].

Figure 1. Custom design metal heating block for in situ chemistry measurements with magnetic hotplate stirrer (left); ODISC furnace with quartz tube inside and magnetic stirrer below (middle); ODISC furnace with metal autoclave inside and magnetic stirrer below (right).

For more demanding in situ synthesis – at temperatures above 100oC or in metal autoclaves – the custom designed furnace ODISC was developed on the beamline I12 [3]. The furnace is very versatile with integrated heating, stirring, and precise sample centring and it can be used for a wide range of in situ experiments on the beamline. On the beamline I12, the furnace ODISC can be used in two configurations: 1) in situ measurements of reaction kinetic during solvothermal synthesis experiments, which performed at temperatures below boiling temperature of the solvent. In this case simple quartz tubes are used as a container during large-scale in situ synthesis [4]. 2) in situ measurements of reaction kinetic during hydrothermal synthesis, which should be performed in metal autoclaves. Despite measurements during the crystallization were performed in the metal autoclave, the data quality recorded on the beamline I12 allowed the refinement of the diffraction data and subsequent analysis of crystallization kinetic [5].The references should be in Heading 4 style (Times New Roman 9 pt, shortcut CTRL + NUM 4) and listed immediately at the end of the text without a heading.

[1] Drakopoulos M., Connolley T., Reinhard C., Atwood R., Magdysyuk O., Vo N., Hart M., Connor L., Humphreys B., Howell G., Davies S., Hill T., Wilkin G., Pedersen U., Foster A., De Maio N., Basham M., Yuan F., Wanelik K. J. (2015). Synchrotron Rad. 22, 828.

[2] Yeung H.H-M., Sapnik A.F., Massingberd-Mundy F., Gaultois M.W., Wu Y., Fraser D.A.X., Henke S., Pallach R., Heidenreich N., Magdysyuk O.V., Vo N.T., Goodwin A.L. (2019). Angew. Chem., Int. Ed., 58, 566.

[3] Moorhouse S.J., Vranješ N., Jupe A., Drakopoulos M., O’Hare D. (2012). Rev. Sci. Instr. 83, 084101

[4] Cliffe M.J., Castillo-Martínez E., Wu Y., Lee J., Forse A.C., Firth F.C.N., Moghadam P.Z., Fairen-Jimenez D., Gaultois M.W., Hill J. A., Magdysyuk O.V., Slater B., Goodwin A.L., Grey C.P. (2017). J. Am. Chem. Soc. 139, 5397.

[5] Cook D.S., Wu Y., Lienau K., Moré R., Kashtiban R.J., Magdysyuk O.V., Patzke G.R., Walton R.I. (2017). Chem. Mater. 29, 5053–2057.



10:55am - 11:25am
ID: 336 / MS-76(59b): 3
Bursary application
Oral/poster
MS: High pressure crystallography, Solid state reactions and dynamics, Crystal chemistry with emerging technology
Keywords: organometallic chemistry, B-H bond activation, pincer complexes, high-pressure crystallography

The solid-state chemistry of rhodium(I) pincer complexes under extreme conditions.

Alexandra Longcake, Jeremiah P. Tidey, Mark S. Senn, Adrian B. Chaplin

University of Warwick, Coventry, United Kingdom

The activation of B-H bonds in σ-borane complexes is of interest not only due to their applications in catalysis (hydroborations, borylations), but because of the ambiguity of σ-borane coordination modes, which can be challenging to formerly define.[1] Because σ-borane complexes are intermediates to B-H activation, they can be difficult to study due to the transience of the highly reactive species.

The σ-borane complexes [Rh(PONOP)(ɳ2-HBR)][BArF4], (PONOP = 2,6-Bis(di-tert-butyl-phosphinito)pyridine; ArF = 3,5‑Bis(trifluoromethyl)phenyl; HBR = HBcat: 1; HBR = HBpin: 2) have been synthesised in good yields and have been established to undergo oxidative addition (OA) in solution at modest temperatures (< 75 °C). However, the OA products were unstable in solution, preventing their full characterisation using traditional solution-based methods. A single crystal high-pressure study of 1 was undertaken up to pressures of 25.8 kbar. An isomorphous phase transition was observed between the pressures of 4.8 and 8.8 kbar, which was accompanied by several geometrical rearrangements of the HBcat ligand with respect to the remainder of coordination complex. Most notably, the decrease in the N-Rh-B bond angle of ca. 6 ° across the phase transition suggests an increased overlap between the metal d orbital and the ‘empty’ boron orbital, indicating a stronger interaction between the metal centre and the σ-borane ligand. [2]

We aim to further the understanding of B-H bond activation by studying σ-borane complexes using high-pressure X-ray diffraction (HP-XRD) as the principal analytical tool. Precise structural determination and analysis of a systematic series of σ-borane complexes will ultimately allow for better modelling of their reactive transition states in associated catalytic cycles, ultimately enabling better targeted design of industrially relevant catalysts.

[1] Hebden, T. J.; Denney, M. C.; Pons, V.; Piccoli, P. M. B.; Koetzle, T. F.; Schultz, A. J.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. (2008) J. Am. Chem. Soc. 130, 10812–10820.

[2] Marder, T. B.; Lin, Z., Contemporary Metal Boron Chemistry I. Springer-Verlag: Berlin Heidelberg, 2008; Vol. 130, p 125-127.

Keywords: organometallic chemistry; B-H bond activation; pincer complexes; high-pressure crystallography

Alex Longcake acknowledges the Royal Society for a PhD studentship (RGFEA180160) and Diamond Light Source for time on Beamline I19 under proposal CY26847.

Bibliography
N/A


11:25am - 11:45am
ID: 807 / MS-76(59b): 4
Chemical crystallography, crystal structures
Oral/poster
MS: Graphs, tilings and crystal structures, Complex structures of minerals and inorganic materials, Solid state reactions and dynamics, Crystal chemistry with emerging technology
Keywords: Disorder, Fuel Cells, Density Functional Theory, Fergusonite, Phase Transitions

Insight into the Structural Variations of Fergusonite-Type Structures: Combined Experimental and Computational Studies

Bryce Mullens1, Maxim Avdeev1,2, Helen Brand3, Subrata Mondal4, Ganapathy Vaitheeswaran5, Brendan Kennedy1

1School of Chemistry, The University of Sydney, New South Wales 2006, Australia; 2Australian Nuclear Science and Technology Organisation, Lucas Heights, New South Wales 2234, Australia; 3Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 2168, Australia; 4Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Prof. C. R. Rao Road, Gachibowli, Hyderabad 500 046, Telangana, India; 5School of Physics, University of Hyderabad, Prof. C. R. Rao Road, Gachibowli, Hyderabad 500 046, Telangana, India

The development of carbon-neutral energy-generation is critical to combatting climate change. One such technology is the development of next-generation ion conductors for solid-oxide fuel cells (SOFCs). SOFCs offer a much more efficient method to extract energy from hydrogen or hydrocarbon fuels than current combustion engines due to their one-step chemical process. However, a bottleneck to the large-scale uptake of SOFCs is the poor performance of the conducting electrolytes that separate the anode from the cathode. Various lanthanoid fergusonite structures (LnBO4) have recently been proposed as solid electrolyte candidates in solid-oxide fuel cells, with increased high-temperature ionic conductivity being measured in chemically doped lanthanum orthoniobates (LaNbO4) [1]. However, a phase transition from I2/a to I41/a within the operational temperature of SOFCs makes these structures non-ideal.

To understand the effects of chemical doping on the structure and electrochemical properties of these fergusonite structures, several complex fergusonites have been investigated [2-3]. Of interest is the substitution of NbV for TaV on the B-site, which has shown a decrease in the unit cell volume of the structure [4]. This is particularly remarkable, given the two metal cations have the same ionic radius and Ta has an extra 5d valence shell compared to the 4d shell of Nb. Such substitution has further shown to increase the I2/a to I41/a first-order phase transition temperature, highlighting the potential of the properties of these structures to be specifically ‘tailored’ to be used for SOFCs.

Various solid-solution series of Ln(Nb1-xTax)O4 (Ln = La-Lu) have been synthesised using conventional solid-state methods. Synchrotron X-ray and neutron powder diffraction methods have been used to investigate their structures, focusing on changes in both their unit cell volumes and the temperature of the I2/a to I41/a phase transitions. Whilst the fergusonite structure is a monoclinic structure derived of the tetragonal scheelite aristotype, it’s structure is based on BO6 polyhedra as opposed to BO4 scheelite polyhedra. These studies have revealed several anomalies, revealing that different structures can be isolated by controlling the size of the Ln ion and synthetic conditions, and that the volume of the BO6 polyhedra and length of the B–O bonds change depending on its surrounding Ln ion. This data surprisingly implies that the AO8 polyhedra act as a rigid framework in which the BO6 polyhedra respond. The experimental data has been further reinforced by ground state energy calculations performed using density functional theory. This is a landmark accomplishment that has not been previously used in similarly studied structures. These insights can be used in the development and engineering of novel and advanced electrolyte materials for SOFCs.

[1] - Cao, Y.; Duan, N.; Yan, D.; Chi, B.; Pu, J.; Jian, L.; Enhanced Electrical Conductivity of LaNbO4 by A-Site Substitution. Int. J. Hydrogen Energy, 2016, 41 (45), 20633-20639.

[2] - Arulnesan, S. W.; Kayser, P.; Kimpton, J. A.; Kennedy, B. J.; Studies of the Fergusonite to Scheelite Phase Transition in LnNbO4 Orthoniobates. J. Solid State Chem., 2019, 277, 229-239.

[3] - Ivanova, M.; Ricote, S.; Meulenberg, W. A.; Haugsrud, R.; Ziegner, M.; Effects of A- and B-Site (Co-)Acceptor Doping on the Structure and Proton Conductivity of LaNbO4. Solid State Ionics, 2012, 213, 45-52.

[4] – Mullens, B. G.; Avdeev, M.; Brand, H. E. A.; Vaitheeswaran, G.; Kennedy, B. J.; Insights into the Structural Variations in SmNb1-x­TaxO4 and HoNb1-xO4 Combined Experimental and Computational Studies. Under Revision for Dalton Transactions.



11:45am - 12:05pm
ID: 896 / MS-76(59b): 5
Bursary application
Oral/poster
MS: Crystal chemistry with emerging technology, Crystallization mechanisms of small molecule systems
Keywords: Na2W2O7; Czochralski technique; scintillators; elementary particles; luminescence

Growth and spectroscopic studies of Na2W2O7 crystals doped with Ce+4 and Cr+3 ions, promising scintillation detectors of elementary particles

Veronika Grigorieva, Mariana Rakhmanova, Alexey Ryadun

Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation

Studies of "dark matter" is an important fundamental branch of modern cosmology and theoretical physics. Cryogenic scintillation detectors based on single crystals of tungstates (ZnWO4, CaWO4, Na2W2O7) can be used to register "dark matter"; they register extremely rare signals of interaction of Weakly Interacting Massive Particles (WIMP) with the nuclei of the detector material [1].

The important requirements to scintillation materials for the search and registration of such rare events are luminescence, light yield, energy resolution, high level of radiation purity. Necessary radiation purity level and optical quality of scintillators require the development of special technologies for deep purification of starting materials and new approaches to crystal growth under conditions of low temperature gradients, the production of scintillation elements with a high utilization rate of the costly starting material. Scintillation bolometers based on Na2W2O7 must also be of high mechanical strength for their practical significance since bolometric elements of specified form will have to be cut from the crystals. To improve the mechanical and optical characteristics, charge with chromium Cr+3 and cerium Ce+4 doping was prepared, doped Na2W2O7 crystals were grown and their luminescent properties were investigated [2].

Na2W2O7 crystals were grown from melt by low-thermal-gradient Czochralski technique (LTG Cz) developed at NIIC SB RAS (Novosibirsk, Russia). Major difference from conventional Czochralski technique is in temperature gradients reduced by two orders of magnitude, below 1 K/cm. Main advantages of LTG Cz are reduced thermoelastic stresses in growing crystals so that they don’t influence crystal quality, and suppression of melt components decomposition and volatilization. By LTG Cz many scintillating crystals of record size and optical quality were obtained, such as BGO, CdWO4 and many other [3].

As precursors, Na2CO3, WO3, CeO2, TiO2 and Cr2O3 powders were used. Initial charge for crystal growth was prepared by solid-state synthesis at 400 °C in muffle furnace according to the reaction:

Na2CO3 + 2WO3 → Na2W2O7 + CO2

Completeness of synthesis was controlled by weight change due to CO2 volatilization. Crystallization rate was set at 1.5 mm/h, rotation velocity at 10 rev/min. Diameter of grown Na2W2O7 crystals was 30 mm, length up to 70 mm and 40 mm for pure and doped ones, correspondingly.

[1] Indra, Raj, Kim, H.J., Lee, H.S., Kim, Y.D., Lee, M.H., Grigorieva, V.D., Shlegel, V.N. (2018) Eur. Phys. J. C, 78, 973. [2] Ryadun, A.A., Rakhmanova, M.I., Grigorieva, V.D. (2020) Optical Materials, 99, 109537. [3] Shlegel, V.N., Borovlev, Yu.A, Grigoriev, D.N, Grigorieva, V.D. et al. (2017) JINST, 12, C08011.

Keywords: Na2W2O7; Czochralski technique; scintillators; elementary particles; luminescence

This work was supported by Russian Foundation for Basic Research (grant No. 20-43-543015).

Bibliography
In last 5 years, indexed in Scopus and WebofSci, 4 publications by first authorship, 25 in total:
1.Grigorieva V.D., Ivannikova N.V., Ivanov I.M., Makarov E.P., Shlegel V.N. «Precursors preparation for growth of low-background scintillation crystals» AIP Conference Proceedings, 2018, Vol. 1921.
2.Grigorieva V.D., Shlegel V.N., Ivannikova N.V., Bekker T.B., Yelisseyev A.P., Kuznetsov A.B. «Na2Mo2O7 scintillating crystals: Growth, morphology and optical properties» Journal of Crystal Growth, 2019, 507, 31-37.
3.Grigorieva V.D., Shlegel V.N.; Borovlev Y.A.; Ryadun A.A.; Bekker T.B. “Bolometric molybdate crystals grown by low-thermal-gradient Czochralski technique” Journal of Crystal Growth, 2019, V. 523. P. 125144.
4.V.D. Grigorieva, V.N. Shlegel, Yu.A. Borovlev, T.B. Bekker, A.S. Barabash, S.I. Konovalov, V.I. Umatov, V.I. Borovkov, O.I. Meshkov “Li2100deplMoO4 crystals grown by low-thermal-gradient Czochralski technique” Journal of Crystal Growth, 2020, V. 552, 125913.

5.T. B. Bekker, N. Coron, F. A. Danevich, V. Ya. Degoda, A. Giuliani, V. D. Grigorieva, N. V. Ivannikova, M. Mancuso, P. de Marcillac, I. M. Moroz, C. Nones, E. Olivieri, G. Pessina, D. V. Poda, V. N. Shlegel, V. I. Tretyak, M. Velazquez «Aboveground test of an advanced Li2MoO4 scintillating bolometer to search for neutrinoless double beta decay of Mo-100» Astroparticle Physics, 2016, V. 72, pp. 38–45.
6.P. A. Popov, S. A. Skrobov, N. V. Mitroshenkov, V. N. Shlegel, V. D. Grigorieva, «Thermal Conductivity of Na2W2O7 Crystal» Physics of the Solid State, 2016, V. 58, No. 8, pp. 1716–1718.
7.Armengaud E., Augier C., Barabash A.S., Grigorieva V.D. et al. «Development of 100Mo-containing scintillating bolometers for a high-sensitivity neutrinoless double-beta decay search» European Physical Journal C, 2017, 77:785.
8.Shlegel V.N., Borovlev Yu.A, Grigoriev D.N., Grigorieva V.D., Danevich F.A., Ivannikova N.V., Postupaeva A.G., Vasiliev Ya.V. «Recent progress in oxide scintillation crystals development by low-thermal gradient Czochralski technique for particle physics experiments» Journal of Instrumentation, 2017, Volume 12 C08011.
9.Pandey Indra Raj, Kim H.J. , Lee H.S., Kim Y.D., Lee M.H., Grigorieva V.D., Shlegel V.N. «The Na2W2O7 crystal: a crystal scintillator for dark matter search experiment» European Physical Journal C, 2018, 78:973.
10.Solntsev V.P., Bekker T.B., Davydov A.V., Yelisseyev A.P., Rashchenko S.V., Kokh A.E., Grigorieva V.D., Park S.-H.. «Optical and Magnetic Properties of Cu-Containing Borates with "antizeolite" Structure» Journal of Physical Chemistry C, 2019, V. 123, I. 7, 21, 4469-4474.
11.Matskevich N.I., Shlegel V.N., Stankus S.V., Grigorieva V.D., Samoshkin D.A., Zaitsev V.P., Kuznetsov V.A. “New mixed oxides on the basis of bismuth niobate and lithium molybdate” Materials Today: Proceedings, 2019, 25, с. 367-369.
12.Alenkov V., Bae H.W., Beyer J., Grigoryeva V.D., Makarov E.P., Shlegel V.N. et al. «First results from the AMoRE-Pilot neutrinoless double beta decay experiment» European Physical Journal C, 2019, Volume 79, Issue 9, 791.
13.Armengaud, E., Augier, C., Barabash, Grigorieva V.D., A.S., Yakushev, E., Zolotarova, A.S. et al. “Precise measurement of 2ν2β decay of 100Mo with Li2MoO4 low temperature detectors: Preliminary results” AIP Conference Proceedings, 2019, 2165, 020005.
14.Armengaud E., Augier, C., Barabash A.S., Borovlev Yu.A., Grigorieva V.D., Makarov E.P., Shlegel V.N., Yakushev E., Zolotarova A.S. et al. “The CUPID-Mo experiment for neutrinoless double-beta decay: performance and prospects” European Physical Journal C, 2020, 80(1), 44.
15.Ryadun A.A., Rakhmanova M.I., Grigorieva V.D. «Photoluminescence properties of perspective bolometric crystals Na2Mo2O7 and Na2W2O7 grown by low-thermal-gradient Czochralski technique» Optical Materials, 2020, 99, 109537.
16.Degoda V.Y., Danevich F.A., Grigorieva V.D., Pogust G.P., Shlegel V.N., Stanovyy O. “Luminescence of Li2W1-0.05Mo0.05O4 crystal under X-ray excitation” Optik, 2020, 206, 164273.
17.Ryadun A.A., Rakhmanova M.I., Grigorieva V.D. «Effect of Cu doping on properties of PbMoO4 single crystals as materials for luminescence thermometry» Materials Technology, 2020.
18.Kowalczyk M., Ramazanova T.F., Grigoryeva V.D., Shlegel V.N., Kaczkan M., Fetliński B., Malinowski M. “Optical investigation of Eu3+ doped Bi12GeO20 (BGO) crystals” Crystals, 2020, 10(4), 285..
19.Armengaud, E., Augier, C., Barabash, A.S., Borovlev Yu. A., Grigorieva V.D., Makarov E.P., Shlegel V.N., Yakushev, E., Zolotarova, A.S. et al. “Precise measurement of 2νββ decay of 100 Mo with the CUPID-Mo detection technology” European Physical Journal C, 2020, 80(7), 674.
20.Musikhin, A.E., Bespyatov, M.A., Shlegel, V.N., Grigorieva, V.D. "Thermodynamic properties and phonon density of states of Na2Mo2O7 using heat capacity measurements from 5.7 to 310 K” Journal of Alloys and Compounds, 2020, 830,154592.
21.I. Novoselov, O.V. Gileva, J.S. Choe, K.A. Shin, V.N. Shlegel’, V.D. Grigorieva, M.H. Lee, Y.Kim, H.K. Park «Preparation of Extra-pure Na2CO3 Powder with Crystallization Techniques for Low-Background Scintillation Crystal Growth» Inorganic Materials, 2020, 56(8), pp. 867-874.
22.S. Nagorny, C. Rusconi, S. Sorbino, J.W. Beeman, F. Bellini, L. Cardani, V.D. Grigorieva, L. Pagnanini, S. Nisi, I.I. Novoselov, S. Pirro, K. Schäffner, V.N. Shlegel “Na-based crystal scintillators for next-generation rare event searches” Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2020, 977, 164160.
23.Chunaev D.S., Lukanin V.I., Shukshin V.E., Zverev P.G., Shlegel V.N., Grigorieva V.D. «Stimulated Raman scattering in disodium ditungstate crystal» Laser Physics Letters, 2020, 17(1), 015801.
24.Matskevich N.I., Shlegel V.N., Stankus S.V., Grigorieva V.D., Samoshkin D.A., Zaitsev V.P., Kuznetsov V.A. “New mixed oxides on the basis of bismuth niobate and lithium molybdate” Materials Today: Proceedings, 2020, 25, с. 367-369.
25.Ryadun A.A., Rakhmanova M.I., Grigorieva V.D. “Optical properties of Pb2MoO5 and Pb2WO5 single crystals as materials for practical applications” Optik, 2020, 165912


12:05pm - 12:25pm
ID: 268 / MS-76(59b): 6
Bursary application
Oral/poster
MS: Crystal chemistry with emerging technology
Keywords: semi-organic compounds, NLO properties, THG technique, correlation

Correlation between structural studies and third order NLO properties of three new semi-organic compounds

Rim Benali-Cherif1, Radhwane Takouachet1, El-Eulmi Bendeif2, Nourredine Benali-Cherif3

1Abbes Laghrour Khenchela University, Khenchela, Algeria; 2Laboratoire de Cristallographie, Résonance Magnétique et Modélisations (CRM2, UMR CNRS 7036). France; 3Houari Boumédiène (USTHB)-Member of Algerian Academy of Sciences and Technology (AAST) Algiers. Algeria

Correlation between structural studies and third order NLO properties

of three new semi-organic compounds

R. Benali-Cherif R1, R. Takouachet 1, E-E Bendeif2, N. Benali-Cherif R3

1Abbes Laghrour Khenchela University. Algeria, 2 Laboratoire de Cristallographie, Résonance Magnétique et Modélisations (CRM2, UMR CNRS 7036). France, 3 Houari Boumédiène (USTHB) and Member of Algerian Academy of Sciences and Technology (AAST) Algiers. Algeria Algeria

The study of semi-organic compounds has been of growing interest for a few years. In addition to their fundamental interest in the nature of the bonds occurring between inorganic anions and organic cations, these compounds also have remarkable physico-chemical and optical properties. Recently, the variety of semi-organic hybrid crystals has been developed for NLO applications. The combination of organic compounds, especially amino acids with mineral acids, gives rise to new hybrid crystals with strong NLO properties.Semi-organic compounds play an important role in cell metabolism; they intervene in transfer of energy because of their richness in hydrogen bonds. Inter-ionic interactions through the hydrogen bridges present in this type of semi-organic compounds can serve as mimes explaining some bio-inorganic mechanisms.

Measurement of nonlinear third order electrical susceptibilities was performed for three new compounds (Table 1) by the Third Harmonic Generation (THG) technique. Figure 1 shows the intensity of the THG signal as a function of the angle of incidence, it exhibits the same behavior as the silica.

Table 01. Experimental values of nonlinear susceptibility of the third order.

The third order nonlinear electrical susceptibility values of studied compounds are stronger than that of silica (reference material). The largest value is observed for the first compound, = 9,63×10-21 m2/V2 (Table 1) due to the increase in charge transfer and the large number of hydrogen bonding which increases the dipole moment of the compound .

Figure 1. Intensity of the third harmonic for the three samples

These optical measurements revealed different optical behaviors of the three compounds studied. It is therefore very interesting to analyze and discuss the different structural factors correlated with these interesting physical properties. Several structural parameters affect the physical and optical properties of these materials such as: atomic arrangement, intra- and intermolecular interactions, crystal symmetry and electron density distribution.

Keywords: semi-organic compounds - NLO properties - THG technique

[1] Publication of a book on May 05, 2017 entitled “Corrélations structures propriétés ONL de 3 nouveaux composés hybrides »in the “Éditions Universitaires Européennes »

Bibliography
Falek. W, Benali-Cherif. R, Golea. L, Samai. S, Benali-Cherif. N, Bendeif. E.-E, Daoud. I. Journal of Molecular Structure. 1192 (2019) 132-144

« A structural comparative study of charge transfer compounds: Synthesis, crystal structure, IR, Raman-spectroscopy, DFT computation and hirshfeld surface analysis »


12:25pm - 12:45pm
ID: 231 / MS-76(59b): 7
Bursary application
Oral/poster
MS: Perovskites, Phase transitions in complex materials (structure and magnetism), Crystal chemistry with emerging technology
Posters only: Structure and phase transitions in advanced materials, Chemical crystallography, crystal structures (if it does not fit to any specific topics)
Keywords: Phase transitions, X-ray diffraction, Mössbauer spectrometry, Raman spectroscopy, UV– Vis spectroscopy

Structural, magnetic and optical properties study of tellurium–based: Sr3–xPbxFe2TeO9 (0 ≤ x ≤ 2.25) double perovskites

Abdelhadi El Hachmi1, Bouchaib Manoun1,2, Mohammed Sajieddine3, Peter Lazor4

1Laboratoire Rayonnement Matière et Instrumentation, S3M, FST, University Hassan 1er, 26000 Settat, Morocco; 2Materials Science and nano–engineering (MSN), University Mohammed VI Polytechnic, Lot 660 Hay Moulay Rachid, 43150 Ben Guerir, Morocco; 3Material Physics Laboratory, Faculty of Sciences and Techniques, Sultan Moulay Sliman University, B.P. 523, 23000 Beni–Mellal, Morocco; 4Department of Earth Sciences, Uppsala University, SE–752 36, Uppsala, Sweden

Materials family of A3B’2B’’O9 (A = alkaline–earth metal ions with valence +2, B’ and B’’= transition metal ions with valences +3 and +6 respectively) were subjected to extensive studies, and have attracted significant interest owing to their physical properties and technological applications. The discovery of colossal magnetoresistance (CMR) in the ordered A2B’B’’O6 double perovskite oxides has given rise to many recent research [1–3].

Polycrystalline samples of the series of triple perovskites Sr3−xPbxFe2TeO9 (0 ≤ x ≤ 2.25) were synthesized using solid state reaction [4]. These materials have been studied by a combination of XRPD, Mössbauer spectrometry, Raman and UV–Vis spectroscopies. The crystal structures were resolved by the Rietveld refinement method, and revealed that this Sr3−xPbxFe2TeO9 (0 ≤ x ≤ 2.25) system shows one space group change from tetragonal I4/m (0 ≤ x ≤ 1) to another tetragonal form I4/mmm (1.25 ≤ x ≤ 1.88) and a second transition to hexagonal R-3m (2.08 ≤ x ≤ 2.25). The valence state of iron in the Fe site was determined to be Fe(III) by Mössbauer spectrometry, which also revealed two sites in a concordance with the XRPD measurements. 57Fe Mössbauer spectra measurements show paramagnetic and magnetic ordering behaviors. The observed Raman spectra as a function of composition show obvious changes on the positions (wavenumbers), the FWHM and the intensities of the modes confirming the phase transformations observed by the XRPD results. These structural transitions led to a distinct change in the optical band gap energy, varying from 2.14 to 1.85 eV.

[1] K.I. Kobayashi, T. Kimura, H. Sawada, K. Terakura, Y. Tokura. Nature, 1998, 395, 677–680.
[2] M. García–Hernández, J.L. Martínez, M.J. Martínez–Lope, et al., Phys. Rev. Lett., 2001, 86, 2443.
[3] W.R. Branford, S.K. Clowes, Y.V. Bugoslavsky, et al., J. Appl. Phys., 2003, 94(7), 4714–4716.
[4] A. El Hachmi, F. El Bachraoui, S. Louihi, Y. Tamraoui, S. Benmokhtar, et al., J. Inorg. Organomet. Polym., 30, 1990–2006 (2020). https://doi.org/10.1007/s10904-020-01446-4

Bibliography
A. El Hachmi, B. Manoun, M. Sajieddine, Y. Tamraoui, S. El Ouahbi. Synthesis, structural and optical properties of perovskites–type: Sr3Fe2+xMo1–xO9–3x/2 (x = 0.30, 0.45, 0.60, 0.75 and 1.00). Polyhedron 200 (2021) 115133. https://doi.org/10.1016/j.poly.2021.115133

A. El Hachmi, B. Manoun, Y. Tamraoui, S. Louihi, L. Bih, M. Sajieddine and P. Lazor. Structural and Mössbauer studies of Sr1.5Ca1.5Fe2.25Mo0.75O9–δ and Sr1.92Ca1.08Fe2.04W0.96O9–δ double perovskites. Journal of Structural Chemistry, 61, 861–872 (2020). https://doi.org/10.1134/S0022476620060049

El Hachmi, A., El Bachraoui, F., Louihi, S. et al. ‘Structural, Magnetic and Optical Properties Study of Tellurium–Based Perovskites: Sr3−xPbxFe2TeO9 (0 ≤ x ≤ 2.25)’. Journal of Inorganic and Organometallic Polymers and Materials, 30, 1990–2006 (2020). https://doi.org/10.1007/s10904-020-01446-4