Session | ||
MS-20: Dynamic frameworks
Invited: Hoi Ri Moon (Republic of Korea), Yao Chen (China) | ||
Session Abstract | ||
Dynamic behaviour and structural flexibility are important properties of extended frameworks, such as Metal-organic Frameworks (MOFs), and in porous solids composed of molecular materials, like Metal-organic Polyhedra (MOPs) and Porous Organic Cages (POCs). In extended materials this can be realised as breathing or stimulus-response, providing access to unexpected porosity or sensing behaviour. For molecular materials, which lack strong bonding between components, structural transformations in response to sorbents can be profound, leading to advantageous sorption and separation processes. This session will examine the dynamic behaviour and structural flexibility of both molecular and extended porous frameworks, with a focus on phase transitions, which can be monitored by X-ray crystallography. For all abstracts of the session as prepared for Acta Crystallographica see PDF in Introduction, or individual abstracts below. | ||
Introduction | ||
Presentations | ||
10:20am - 10:25am
Introduction to session 10:25am - 10:55am
Flexible Metal-Organic Frameworks for Hydrogen Isotope Separation Department of Chemistry, Ulsan National Institute of Science and Technology, Ulsan, Korea, Republic of (South Korea) External Resource: https://www.xray.cz/iucrv/vidp.asp?id=172
10:55am - 11:25am
Novel composite platform: Biomolecules-incorporation for biocatalysis, separation and biopharmaceutical formulations Nankai University, Tianjin, China, People's Republic of External Resource: https://www.xray.cz/iucrv/vidp.asp?id=173
11:25am - 11:45am
Dynamic frameworks: the role of non-covalent interactions University of Cape Town, Cape Town, South Africa External Resource: https://www.xray.cz/iucrv/vidp.asp?id=174
11:45am - 12:05pm
Synthesis and structural properties of isostructural Zn(II) M12L8 poly-[n]-catenane using the 2,4,6-tris(4-pyridyl)benzene (TPB) ligand Politecnico di Milano, Milan, Italy External Resource: https://www.xray.cz/iucrv/vidp.asp?id=175
12:05pm - 12:25pm
Cocrystallization, high pressure/low temperature behaviour and vapochromism in a family of aurophilic copper-gold supramolecular networks. 1Department of Chemistry, Università di Torino, Via Pietro Giuria 7, 10125 Torino, Italy; 2Department of Earth sciences, University of Torino, Via Valperga Caluso 35, 10125, Turin, Italy; 33Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale G. P. Usberti 17A, 43100 Parma, Italy External Resource: https://www.xray.cz/iucrv/vidp.asp?id=176
12:25pm - 12:45pm
Structural modifications occurring during the water sorption processes on a potential material for autonomous indoor humidity control 1University of Dschang, Department of Chemistry, PO Box 67, Dschang, Cameroon; 2Fraunhofer-Institut for Solar Energy Systems ISE, Division Thermal Systems and Buildings, Heidenhofstraße 2, 79110 Freiburg, Germany; 3Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany; 4Laboratoire Léon Brillouin (LLB), UMR 12 CEA/CNRS, Bât. 563 CEA Saclay, 91191 Gif-sur-Yvette cedex, France External Resource: https://www.xray.cz/iucrv/vidp.asp?id=177
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