| Session | ||
MS-43: Solid state reactions and dynamics
Invited: Hiroyoshi Ohtsu (Japan), Paolo Pio Mazzeo (Italy) | ||
| Session Abstract | ||
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Chemical reactions and dynamic behavior in the solid-state are intriguing as they allow the understanding of chemical processes that in the solution state are difficult or even not possible. Often unusual reactivity is observed, in part due to the constrained environment brought by the periodic arrangement of molecules or ions in the solid state, but also because of the dynamic properties of the solids. This session will deal with solid-state reactivity in a wide type of materials ranging from porous Metal-Organic Frameworks (MOFs), fluoride materials, soft metal organic complexes, that are exposed to external stimuli such as moisture, guest molecules, light or temperature. The solid-state reactivities presented in this session have used various X-ray crystallographic techniques such as single crystal XRD, powder XRD (Rietveld) and PDF analysis among other techniques to elucidate the solid-state products. For all abstracts of the session as prepared for Acta Crystallographica see PDF in Introduction, or individual abstracts below. | ||
| Introduction | ||
| Presentations | ||
10:20am - 10:25am
Introduction to session 10:25am - 10:55am
Stepwise evolution of molecular nanoaggregates inside the pores of a highly flexible Metal-Organic Framework. 1Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze, 17A, 43124 Parma (Italy); 2Biopharmanet-TEC, Università degli studi di Parma via Parco Area delle Scienze 27/A, 43124 Parma (Italy); 3Elettra—Sincrotrone Trieste S.S. 14 Km 163.5 in Area Science Park, 34149 Basovizza—Trieste (Italy); 4Centro Interuniveristario di Reattività Chimica e Catalisi (CIRCC) Via Celso Ulpiani 27, 70126 Bari (Italy) External Resource: https://www.xray.cz/iucrv/vidp.asp?id=319
10:55am - 11:25am
Kinetic assembly of coordination networks creates flexible and functional materials Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan External Resource: https://www.xray.cz/iucrv/vidp.asp?id=320
11:25am - 11:45am
In-situ XRD and PDF investigation of battery fluoride materials MF3.3H2O (M = Fe, Cr) in controlled atmosphere: accessing new phases with controlled chemistry 1Malvern Panalytical B.V., Almelo, Netherlands, The; 2School of Chemical Science and Engineering, Royal Institute of Technology, Teknikringen 42, SE 100 44 Stockholm, Sweden; 3Université Grenoble Alpes, Institut Néel, F-38042 Grenoble, France External Resource: https://www.xray.cz/iucrv/vidp.asp?id=321
11:45am - 12:05pm
Light- and temperature-induced linkage isomerism in a series of NiII, CuII and CoIII complexes in the solid state 1Department of Chemistry, University of Warsaw, Żwirki i Wigury 101, 02-089 Warsaw, Poland; 2Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland; 3CRM2, Jean Barriol Institute, CNRS UMR 7036, University of Lorraine, BP 70239, Boulevard des Aiguillettes, 54506 Vandoeuvre-lès-Nancy, France External Resource: https://www.xray.cz/iucrv/vidp.asp?id=322
12:05pm - 12:25pm
Studies of the functional characteristics of adaptive X-ray optical elements based on combination of longitudinal and transverse acoustic waves in wide frequency ranges 1NRC “Kurchatov institute”, 1, Akademika Kurchatova pl., Moscow, Russia, 123182; 2FSRC “Crystallography and photonics” RAS, 59, Leninskii pr., Moscow, Russia, 119333; 3Institute of Applied Problems of Physics NAS of Armenia, 25, Hrachya Nersissian Str., Yerevan, Republic of Armenia, 0014; 4Tomsk Polytechnic University, 30, Lenin Avenue, Tomsk, Russia, 634050 External Resource: https://www.xray.cz/iucrv/vidp.asp?id=323
12:25pm - 12:45pm
In situ control of Photochromic properties with dual photoreactive soft crystal Department of Chemistry, Tokyo Institute of Technology, Tokyo, Japan External Resource: https://www.xray.cz/iucrv/vidp.asp?id=324
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