Time: Monday, 16/Aug/2021: 10:20am - 12:45pm Session Chair: Christopher SUMBY Session Chair: Michael John Zaworotko |
Location: Club C 50 1st floor |
Invited: Hoi Ri Moon (Republic of Korea), Yao Chen (China)
Dynamic behaviour and structural flexibility are important properties of extended frameworks, such as Metal-organic Frameworks (MOFs), and in porous solids composed of molecular materials, like Metal-organic Polyhedra (MOPs) and Porous Organic Cages (POCs). In extended materials this can be realised as breathing or stimulus-response, providing access to unexpected porosity or sensing behaviour. For molecular materials, which lack strong bonding between components, structural transformations in response to sorbents can be profound, leading to advantageous sorption and separation processes. This session will examine the dynamic behaviour and structural flexibility of both molecular and extended porous frameworks, with a focus on phase transitions, which can be monitored by X-ray crystallography.
For all abstracts of the session as prepared for Acta Crystallographica see PDF in Introduction, or individual abstracts below.
Introduction to session
Flexible Metal-Organic Frameworks for Hydrogen Isotope Separation
Department of Chemistry, Ulsan National Institute of Science and Technology, Ulsan, Korea, Republic of (South Korea)
Novel composite platform: Biomolecules-incorporation for biocatalysis, separation and biopharmaceutical formulations
Nankai University, Tianjin, China, People's Republic of
Dynamic frameworks: the role of non-covalent interactions
University of Cape Town, Cape Town, South Africa
Synthesis and structural properties of isostructural Zn(II) M12L8 poly-[n]-catenane using the 2,4,6-tris(4-pyridyl)benzene (TPB) ligand
Politecnico di Milano, Milan, Italy
Cocrystallization, high pressure/low temperature behaviour and vapochromism in a family of aurophilic copper-gold supramolecular networks.
1Department of Chemistry, Università di Torino, Via Pietro Giuria 7, 10125 Torino, Italy; 2Department of Earth sciences, University of Torino, Via Valperga Caluso 35, 10125, Turin, Italy; 33Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale G. P. Usberti 17A, 43100 Parma, Italy
Structural modifications occurring during the water sorption processes on a potential material for autonomous indoor humidity control
1University of Dschang, Department of Chemistry, PO Box 67, Dschang, Cameroon; 2Fraunhofer-Institut for Solar Energy Systems ISE, Division Thermal Systems and Buildings, Heidenhofstraße 2, 79110 Freiburg, Germany; 3Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany; 4Laboratoire Léon Brillouin (LLB), UMR 12 CEA/CNRS, Bât. 563 CEA Saclay, 91191 Gif-sur-Yvette cedex, France