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Session Overview
Session
TOM Materials S4: Thin Films and Applications
Time:
Wednesday, 27/Aug/2025:
8:30am - 10:00am

Location: Collegezaal C


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Presentations
8:30am - 8:45am

Flexible glass planar structures fabricated by rf-sputtering

Lam T. N. Tran1,2, Scaria Sudha Maria Lis1, Rathinavelu Sengottaiyan1, Alice Carlotto3, Anna Szczurek4, Rossana Dell'Anna5,1, Bartosz Babiarczu6, Osman Sayginer7, Stefano Varas1, Andrea Vinante1, Silvia Maria Pietralunga8, Justyna Krzak6, Oreste Salvatore Bursi9,1, Daniele Zonta9,1, Anna Lukowiak10, Giancarlo C. Righini11, Vincenzo M. Sglavo12, Maurizio Ferrari1, Alessandro Chiasera1

1IFN-CNR, CSMFO Lab and FBK Photonics Unit, Trento, Italy; 2Dept. of Materials Technology, Faculty of Applied Sciences, HCMC University of Technology and Education; 3FBK-SE center - HyRes; 4Center for Advanced Technologies, Adam Mickiewicz University Poznan, PolandCenter for Advanced Technologies, Adam Mickiewicz University Poznan, Poland; 5FBK-SD Sensors and Devices Center; 6Dept. of Mechanics, Materials and Biomedical Engineering, Wroclaw University of Science and Technology; 7Department of Mechanical Engineering, Temple University; 8IFN-CNR, Milano; 9DICAM, University of Trento; 10ILTSR PAS, Wroclaw; 11IFAC-CNR, MiPLab, Firenze, Italy; 12Department of Industrial Engineering, University of Trento

The benefits in terms of cost efficiency and versatility achieved through the development of flexible and stretchable electronics and optoelectronics have greatly fueled the exploration of flexible photonic technologies. Introducing mechanical flexibility to photonic structures enables novel functionalities, further broadening their range of applications. Alongside advancements in flexible photonics based on organic platforms, an emerging approach is gaining attention, emphasizing the use of inorganic, all-glass ultra-thin structures. For oxide-based materials, their intrinsic properties, such as transparency, high thermal resistance, and chemical stability, can be harnessed within appropriate systems.

We present flexible SiO2/HfO2 one-dimensional photonic crystals, fabricated via radio frequency sputtering. These systems exhibit a pronounced dependence of their optical properties on the angle of light incidence, particularly demonstrating a blue-shift of the stopband and a narrowing of the reflectance window. However, the most remarkable finding lies in the experimental evidence showing that even after breakage, with visible cracks forming in the flexible glass, the multilayer structures largely retain their integrity. This positions them as promising candidates for flexible photonic applications due to their robust optical, thermal, and mechanical stability.

This research is supported by the projects: CANVAS, LEMAQUME-QuantERA, Project PNRR NFFA-DI IR0000015, PRIN 2022 PNRR P2022YM8J3 - NANOSEES, HORIZON-TMA-MSCA-DN Met2Adapt.



8:45am - 9:00am

Design and optimization of a compact prismatic solar concentrator

Franco Trespidi, Mario V. Imperatore, Gianluca Timò

Research on the Energy System - RSE SpA, Italy

This work focuses on the optimization of a compact square prismatic single stage solar concentrator to be realized either with BK7 glass or Silopren plastic. Zemax software is used to simulate and optimize the optical surfaces. The concentrator consists of a spherical surface atop a parallelepiped, placed above an inverted truncated pyramid. The simulated optical efficiency, without any antireflective coating, ranges between 89% and 96%, with a concentration factor of 400 suns, and an acceptance angle ranging between 0.8° and 1.0°. The collection surface is 5x5 mm2, and the total concentrator height is 10 mm. The optics has been designed to operate in micro-concentrating photovoltaic modules.



9:00am - 9:15am

Coating made easy: slot die deposition of oligothiophene-doped PMMA for luminescent solar concentrators

Irene Motta1,2, Andrea Trifoglio3, Massimo Zambianchi3, Manuela Melucci3, Gregorio Bottaro2,4, Lidia Armelao1,4,5

1Department of Chemical Sciences (DiSC), University of Padova, via F. Marzolo 1, 35131 Padova, Italy; 2Institute of Condensed Matter Chemistry and Technologies for Energy (ICMATE), National Research Council (CNR), c/o Department of Chemical Sciences (DiSC), University of Padova, via F. Marzolo 1, 35131 Padova, Italy; 3Institute for Organic Synthesis and Photoreactivity, National Research Council (CNR), Via Piero Gobetti 101, 40129 Bologna, Italy; 4National Interuniversity Consortium of Materials Science and Technology (INSTM), Florence, Italy; 5Department of Chemical Sciences and Materials Technologies (DSCTM), National Research Council (CNR), Piazzale A. Moro 7, 00185 Roma, Italy

This study investigates thiophene oligomers as fluorophores incorporated within poly(methyl methacrylate) (PMMA) films, fabricated using slot die coating. This versatile technique ensures high optical quality and excellent reproducibility of the deposited films, provided reliable coating parameters are established. Optimized coating conditions yielded highly fluorescent films with a thickness of 30 µm, which were then employed to develop Luminescent Solar Concentrators (LSCs). Electrical characterization, conducted in accordance with standard procedures, revealed that oligomers exhibiting larger Stokes shifts demonstrated superior device performance due to reduced re-absorption losses. These findings underscore the potential of thiophene oligomers for efficient LSC applications.



9:15am - 9:30am

Multi-color diamond-saw-diced channel Pr,Gd:LiYF4 waveguide laser

Jonathan Demaimay1, Ji Eun Bae1, Pavel Loiko1, Gurvan Brasse1, Florent Starecki1, Blandine Guichardaz2, Abdelmjid Benayad1, Patrice Camy1, Alain Braud1

1Centre de Recherche sur les Ions, les Matériaux et la Photonique (CIMAP), UMR 6252 CEA-CNRS-ENSICAEN, Université de Caen Normandie, 6 Boulevard Maréchal Juin, 14050 Caen, France; 2Département d’Optique P. M. Duffieux, Institut FEMTO-ST, UMR 6174 CNRS Université de Franche-Comté, 25030 Besançon, France

Ridge low loss (0.16±0.02 dB/cm) waveguides were fabricated in Pr,Gd:LiYF4 epitaxial layers by precision diamond-saw dicing. The red waveguide laser generated 504 mW at 639.7 nm with a slope efficiency of 57.8%, a linear polarization and a laser threshold of 34 mW. Laser operation in the orange and deep red was also demonstrated.



9:30am - 9:45am

From the visible to the near infrared: revealing the optical response of J-aggregates thin films of cyanine dyes

Mari Carmen López González1, Marina García Pardo1, José Nuno Rocha Gama2, Fernando Chacón Sánchez1, Isabel Pastoriza Santos2, Sara Núñez Sánchez3, Rosalía Serna Galán1

1Instituto de Óptica, CSIC, Spain; 2Universidade de Vigo, Spain; 3Instituto de Ciencia de Materiales, CSIC, Spain

J-aggregates thin films of cyanine dyes are very attractive organic nanomaterials formed by highly ordered assembly of supramolecular organic structures. These films show unique spectroscopic properties, making them promising candidates for integration into advanced electronic and photonic devices. Their spectra show very narrow resonances, resulting in spectral regions with high refractive index, comparable to semiconductors, and negative permittivity, similar to metals. This study focuses on the characterization of the optical properties of cyanine J-aggregates thin films, including refractive index and permittivity, in a wide spectral range from visible to near infrared wavelengths. Our findings highlight the potential of these structures for the development of sustainable photonic devices.



9:45am - 10:00am

Using the insulator-metal transition in VO2 thin films for thermal conductivity measurements

Ilaria Delbono1,2, Boris Kalinic1, Carlo Scian1, Irving Alonzo-Zapata3, Frederic Dumas-Bouchiat3, Corinne Champeaux3, Tiziana Cesca1, Giovanni Mattei1, James K. Utterback2, Jose Ordonez-Miranda2

1University of Padova, Physics and Astronomy Department, via Marzolo 8, I-35131 Padova, Italy; 2Sorbonne Université, CNRS, Institut des NanoSciences de Paris, 75005 Paris, France; 3CNRS, IRCER, UMR 7315, University of Limoges, France

This study presents a technique for measuring the thermal conductivity of materials based on the strong reflectance change caused by the insulator-to-metal transition in VO₂ thin films. Unlike conventional pump-probe and frequency-domain thermoreflectance techniques, this approach is based on steady-state optical microscopy. The presented technique involves imaging the metallic domain induced by a continuous-wave laser beam illumination on the VO₂ surface as a function of laser intensity. By fitting the radius-intensity relationship with a theoretical model developed for this purpose, the thermal conductivities of three materials (silica glass, sapphire, and silicon) are accurately determined, yielding values in good agreement with the tabulated data.



 
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